Standard for needlepoint rugs and adhesives limit of harmful substance release

1, scope this standard specifies a rug, needlepoint rugs cushion and adhesives in the limit of harmful substance release, test methods and inspection rules. This standard applies to the production or sale of needlepoint rugss, needlepoint rugs cushion and adhesives. 2, a normative reference files in the files of the following terms by the standard terms of reference and became the standard. References to the date of the all file, modify it all of the subsequent single (not including the contents of the corrigenda) or revision shall not apply to this standard, however, under this standard agreement of the parties are encouraged to establish whether the latest versions of these files can be used. References to the date of the who does not file, its latest version applies to this standard. GB/T15516-1995 formaldehyde of determination acetyl acetone min light spectrophotometry method GB/T16052-1995 workshop air in the styrene of directly into sample gas phase color spectrum determination method GB/T18204.26-2000 public places air in the formaldehyde determination method ISO/DIS16000-6:1999 indoor air 6th Department min–indoor easy volatile sexual organic compounds of determination ISO16017-1:2000 indoor air , and environment air and work places air–using adsorption tube/pyrolysis absorption/capillary gas phase color spectrum instrument for sampling and analysis 3, and terms and defined following terms and defined applies Yu this standard 3.1, and total volatile sexual organic totalvolatileorganiccompounds with gas phase color spectrum non-polarity column analysis retained time in are ethylene and are 16 n-Zhijian and including they zainei of known and unknown of volatile sexual organic compounds. 3.2 entering the cabin, air exchange rate airexchangerate per hour fresh air volume and tank of effective volume ratio in units of hours, held the first party (h-1). 3.3, materials/class loading than productloadingfactor in the exposed surface area of the sample, and compartment of effective volume ratio,the unit is square metres per cubic metre (M2/M3). 3.4, airvelocity by specimen surface the air speed of air flow velocity in units of meters per second (m/s). 4 limits and classification requirements, requirements of 4.1, needlepoint rugs, needlepoint rugs cushion and adhesives limit of harmful substance release individually satisfy the requirements of table 1, table 2, table 3. A grade for eco-friendly products, class b limit of harmful substances emitted from qualifying products. Table 1 needlepoint rugs harmful material release limited units for mg each square hours ordinal harmful material limited-a level b level 1 total volatile sexual organic compounds (TVOC) ¡Ü 0.500 ¡Ü 0.6002 formaldehyde (Formaldehyde) ¡Ü 0.050 ¡Ü 0.0503 styrene (Styrene) ¡Ü 0.400 ¡Ü 0.50044-stupid base ring vinyl (4-Phenylcyclohexene) ¡Ü 0.050 ¡Ü 0.050 table 2 needlepoint rugs liner harmful material release limited units for mg each square hours ordinal harmful material limited-a level b level 1 total volatile sexual organic compounds (TVOC) ¡Ü 1 ¡Ü 1.2002 formaldehyde (Formaldehyde) ¡Ü 0.050 ¡Ü 0.0503 butyl hydroxyl toluene (BHT-butylatedhydroxytoluene) ¡Ü 0.030 ¡Ü 0.03044-stupid base ring vinyl (4-Phenylcyclohexene) ¡Ü 0.050 ¡Ü 0.050 table 3 Carpet adhesive harmful material release limited units for mg each square hours ordinal harmful material limited-a level b level 1 total volatile sexual organic compounds (TVOC) ¡Ü 10 ¡Ü 12.0002 formaldehyde (Formaldehyde) ¡Ü 0.050 ¡Ü 0.05032-b base ethanol (2-ethyl-1-hexanol) ¡Ü 3 ¡Ü 3.5004.2, and label marked in products label Shang , should identifies products harmful material release limited of level. 5, test methods 5.1, test method for limit of harmful substance release under the provisions of Appendix a. 5.2 and hazardous substance analysis methods perform as in table 4. Table 4 harmful material analysis method harmful material analysis method total volatile sexual organic compounds TVOCISO/DIS16000-6:1999 gas phase color spectrum method ISO16017-1:20004-stupid base ring vinyl 4-PCH butyl hydroxyl toluene BHT2-b base ethanol formaldehyde HCHOGB-/T15516-1995 acetyl acetone min light spectrophotometry method GB/T18204.26-2000 phenol reagents min light spectrophotometry method styrene GB/T1602-1995 gas phase color spectrum method 5.3, and test results of calculation under samples analysis results, harmful material release volume by type (1) calculation EF=Cs (N/L) sth sth sth sth sth sth sth sth sth sth sth (1): EF–module released in units of milligrams per square metre and a half hours (mg/m2h); Cs–cabin concentration in units of milligrams per cubic metre (mg/m3); N–cabin air exchange rate, large hours slightly negative one times square (h-1); L–materials/cabin load ratio, the unit is square metres per cubic metre. 6, 6.1, sampling inspection rules random sampling, in batches, batch size and sample size by it to the appropriate product standard. 6.2, 6.2.1, judgment and reinspection rules classification of the products as provided for in this standard 4.1 judgment. 6.2.2, type inspection sampling products if “limited edition” excessive, is sentenced to the products are not eligible. 6.2.3, where the change process and the formulation of new products must be carried out by the inspection, after passing can be put into production. 6.2.4, when only one is not qualified in the inspection items, allow the products double reinspection. All re-inspection qualified you can determine the qualified products. Appendix a (normative appendix) small environmental test chamber method A.1, a small environmental test class small environmental testing consists of sealed cabin, air filter, air temperature and humidity control and monitoring system, air flow, flow control decoration, air sampling system components. As shown in Figure A.1. 1-air inlet; 2-air filter; 3-air temperature and humidity regulation system; 4-5-air flow regulator air flow regulator; 6-sealCabin; 7-air speed and air cycle of control device; 8-temperature and humidity sensor; 9-temperature and humidity of monitoring system; 10-exhaust mouth; 11-air sampling of set tracheal it is simulation indoor environment, in must of test conditions Xia (temperature, and humidity, and air velocity and air exchange rate,), will sample exposure in cabin within, continued must time Hou, collection cabin within harmful gas. A.2, small environmental test chamber test methods–air temperature 23 ¡ã c ¡À 1 ¡ã c; 50% ¡À 5.0%;—-air relative humidity air 1.0h-1;–air velocity exchange rate 0.1M/s~0.3M/s. A.3, sampling, packaging and preparing of test specimens A.3.1, A.3.1.1 for sampling, sample from regular party production, machine under no more than 30 days, drawn by inspection of packaging products. A.3.1.2, in volume products in the sample, from the head-end 2m, interception of 1m2 sample for at least two blocks in the middle. A.3.1.3, tile needlepoint rugs randomly from the batch product box. A.3.1.4 randomly from the batch product, Carpet adhesive a barrel. A.3.2, packaging and needlepoint rugs production direction of A.3.2.1, constant volume sample into volume, rope fastening, inert sample should be wrapped in airtight packaging bag. For example, you can sample package aluminum foil, enclosed in a gas-tight polyethylene bag, each bag can only load a sample. A.3.2.2, from selected samples to install inside the bag, shall not exceed 1h. And immediately send the test Chamber. A.3.2.3 package, sample tags should be more marked product type, manufacturing date, batch number and manufacturer name. A.3.3 A.3.3.1, and sample, the client samples reach the laboratory as soon as possible after the examination. A.3.3.2, needlepoint rugs and needlepoint rugs cushion edge from the samples must be at least 100mm of the sample, according to the requirements of area of interception of a specimen, the material/cabin load ratio of 0.4m2/M3. A.3.3.3, tile needlepoint rugs should be in the middle of the box parts take samples. Sample A.3.3.4, Carpet adhesive: adhesive coating simulation Board (glass or stainless steel), its material/cabin load ratio of 0.012m2/M3 coating density (mg/cm2) in accordance with the manufacturer’s instructions for use. A.4, space test program A.4.1, test preparation A.4.1.1, test forward cabin cleaning, first alkaline cleaning agent cleaning Chamber wall, then scrubbed with deionized water or distilled water twice, and then purification. A.4.1.2 within and under the test conditions to spaces after leads to purification of clean air. A.4.1.3, in tests before the start of monitoring test conditions such as temperature and humidity, air velocity, air tightness, cabin air background concentrations should be below the detection limit analysis method. A.4.1.4, client sample should blanket face tile on bilge, air flow from the specimen surface evenly through the air. A.4.2, test end test specimen under test conditions in the cabin when emission duration is 24h. A.5, small pilot cabin air sampling method of sampling in accordance with the provisions of ISO16017-1:2000. Reference literature 1, and ENV13419-1Bulidingproducts-Determinationoftheemissionofvolatileorganiccompounds-Part1:Emissiontestchambermethod building products–easy volatile organic compounds of emissions volume of determination 1th Department min: emissions detection cabin test method 2, and ENV13419-3Bulidingproducts-Determinationoftheemissionofvolatileorganiccompounds-Part3:Procedureforsampling,storageandpreparationoftestspecimen building products-easy volatile organic compounds of emissions volume of determination 3rd Department min : samples of select and storage of program and sample of prepared 3, and ASTMD5116-97StandardGuideforSmall-ScaleEnvironmentalChamberDeterminationsofOrganicEmissionsFromIndoorMaterials/Products by indoor material and/or products emissions of organic emissions property of small environment detection cabin determination of standard Guide 4, and EmissionsofVolatileOrganicCompoundsfromNewCarpetsinaLarge-ScaleEncironmentalChamber using large detection cabin determination new needlepoint rugs of easy volatile organic compounds (VOC) emissions volume (author: AlfredT.Hodgeson,JohnD.WooleyandJoanM.Daisey)